Citations with the tag: CROWN ethers
Results 1 - 50
- Synthesis of the first dibenzo(perhydrotriazino)-aza-14-crown-4 ethers.
Chuong Hong Hieu; Le Tuan Anh; Levov, A. N.; Nikitina, E. V.; Soldatenkov, A. T. // Chemistry of Heterocyclic Compounds; Nov2009, Vol. 45 Issue 11, p1406
A letter to the editor is presented regarding synthesis of the first dibenzo(perhydrotriazino)-aza-14-crown-4 ethers.
- An original approach to the amination of crown ethers.
Lyakhovnenko, A. S.; Aksenov, A. V.; Kugutov, M. M. // Chemistry of Heterocyclic Compounds; Dec2010, Vol. 46 Issue 9, p1138
A letter to the editor is presented on the issue of amination of crown ethers.
- Novel method for the acetamination of crown ethers.
Aksenov, A. V.; Aksenov, N. A.; Nadein, O. N.; Aksenova, I. V. // Chemistry of Heterocyclic Compounds; Feb2011, Vol. 46 Issue 11, p1405
A letter to the editor is presented regarding the use of nitroethane-phenylpropanolamine (PPA) for crown ether acetaminations.
- Sugar Derived Crown Ethers and Their Analogs: Synthesis and Properties.
Jarosz, Slawomir; Listkowski, Arkadiusz // Current Organic Chemistry; Apr2006, Vol. 10 Issue 6, p643
Receptors with the sugar unit incorporated into the macrocyclic structure - their synthesis and complexing abilities - are reviewed. The receptors with the disaccharide moieties (although such derivatives are rare) including sucrose are also described in this review.
- Effect of the Structure and Concentration of Crown Ethers on the Electrodeposition of Cadmium and Nickel from Sulfate Electrolytes.
Kuznetsov, V.V.; Skibina, L.M.; Levochkin, R.A.; Vertii, I.V. // Protection of Metals; Mar/Apr2003, Vol. 39 Issue 2, p154
The effectiveness of crown ethers (CEs) at cadmium was found to mainly depend on the character of metal-additive complexation. The formation of electroactive complexes in the bulk of solution usually facilitates the electrode reaction. In contrast, the interaction of metal ions with adsorbed CE...
- FILMS BASED ON GELATIN WITH INCLUDED CROWN-ETHERS FOR DETECTION OF CALCIUM CATIONS.
ZAIYTSEV, S. Yu.; TSARKOVA, M. S.; TIMONIN, A. N.; ZAIYTSEV, I. S.; DMITRIEVA, S. N.; GROMOV, S. P. // Izvestiya Vysshikh Uchebnykh Zavedenii. Seriya Khimiya i Khimich; 2011, Vol. 54 Issue 8, p29
The novel method of investigation of the crown-ethers selective to the calcium cations - "method of three solutions" - was developed. By means of those method peculiarities of complexation of some derivatives of crown ethers and calcium cations have been studied. The novel recipe of preparation...
- Synthesis of novel cyclophane-type crown ethers from 2-methylindole.
Eshghi, Hossein; Rahimisadeh, Mohammad; Pordel, Mehdi; Bakhtiarpoor, Zahra // Journal of Chemical Research; Oct2013, Vol. 37 Issue 10, p596
New indolyl crown ethers were obtained from reaction of bis-indolyl podand with different aldehydes using Fe(HSO4)3 as catalyst. Spectral characterisations and optimised structures of isomers of these new cyclophane-type compounds are also presented.
- Oxidative coupling of naphtho-9-crown-3 ether: X-ray crystal structure and solution and solid-state NMR analysis of the dimer.
Buchanan, G W; Rastegar, M F; Yap, G PA; Moghimi, A; Ghandi, M // Canadian Journal of Chemistry; Oct2001, Vol. 79 Issue 10, p1505
Treatment of naphtho-9-crown-3 ether with FeCl[sub 3 ] and aqueous H[sub 2] SO[sub 4] generates bis-naphtho-9-crown-3 ether in ca. 30% yield. This compound crystallizes in the monoclinic P2[sub 1] /n space group; a = 9.2004(9), b = 18.0868(17), and c = 13.2078(13) Ã…, Î² = 97.799(2)Â° and...
Vshivtsev, V. Yu.; Levanova, E. P.; Grabel'nykh, V. A.; Sukhomazova, E. N.; Zhanchipova, E. R.; Klyba, L. V.; Albanov, A. I.; Russavskaya, N. V.; Sinegovskaya, L. M.; Korchevin, N. A. // Russian Journal of Organic Chemistry; Oct2007, Vol. 43 Issue 10, p1561
The article focuses on the importance of the molecular compound in 3-Oxapentane-1,5-diselenol for the synthesis of efficient complexing ligands, particularly of selenium analogs of crown ethers. The author says that they formerly synthesized 1,3-propanediselenol by reductive cleavage of...
- Synthesis of supramolecular complexes based on tetracrown-substituted zinc porphyrinates.
Mikhailitsyna, E.; Tyurin, V.; Beletskaya, I. // Protection of Metals & Physical Chemistry of Surfaces; Nov2010, Vol. 46 Issue 6, p655
New metal-porphyrin receptors functionalized by aza-crown-ether groups were synthesized. Main paths of supramolecular self-assembly of porphyrin aza-crown-ether conjugates to bis-porphyrin sandwich complexes with metal and ammonium cations were studied using spectral methods of analysis (EAS, H,...
- Thermodynamics of complex formation in mixed solvents K and Î” H for the formation reaction of [Gly18C6] at 298.15 K.
Matteoli, E.; Lepori, L.; Usacheva, T. R.; Sharnin, V. A. // Journal of Thermal Analysis & Calorimetry; Sep2009, Vol. 97 Issue 3, p811
The influence of H2Oâ€“EtOH and H2Oâ€“Acetone mixed solvents at various compositions on the thermodynamics of complex formation reaction between crown ether 18-crown-6 (18C6) and glycine (Gly) was studied. The standard thermodynamic parameters of the complex [Gly18C6] (log KÂ°,...
- Urea nitrate, an exceptionally easy-to-make improvised explosive: studies towards trace characterization.
Tamiri, Tsippy; Rozin, Rinat; Lemberger, Nitay; Almog, Joseph // Analytical & Bioanalytical Chemistry; Sep2009, Vol. 395 Issue 2, p421
Urea nitrate is a powerful improvised explosive, frequently used by terrorists in the Israeli arena. It was also used in the first World Trade Center bombing in New York in February 1993. It is difficult to identify urea nitrate in post-explosion debris, since only a very small fraction survives...
- Interlocked molecules: Tangled tetrahedra.
Cantrill, Stuart // Nature Chemistry; Jun2013, Vol. 5 Issue 6, p442
The article reports on the research of a team in Cambridge and Berlin headed by Christoph Schalley, in which they produce an unusual catenane through six crown ethers that were threaded to the edge of a metal-organic tetrahedron.
- Synthesis Of Schiff's Base Ligands By Condensation Of 2-hydroxyacetophenone And Chiral Diamines.
Agrawala, Manoj Kumar; Kaushik, Manish; Singhalc, Amit // Indian Streams Research Journal; Sep2012, Vol. 2 Issue 8, Special section p1
Three optically active Schiff-base ligands 2-4 have been prepared by thermal condensation of 2-hydroxyacetophenone 1 with (1R,2R)-(-)-1,2-diaminocyclohexane, (1S,2S)-(-)- 1,2-diphenylethylenediamine or R-(+)-2,2'-diamino-1,1'-binaphthalene, respectively. The products have been characterized by...
- Crown ethers: From ion recognition to supramolecular function.
Yadav, G.D. // Chemical Business; Nov97, Vol. 11 Issue 4, p21
Reports that combination of crown ether chemistry with other chemicals can create a functional supramolecular systems.
- Dibenzotetraazamacroheterocycles: Synthesis and properties. (Review).
Kulikov, O. V.; Pavlovsky, V. I.; Andronati, S. A. // Chemistry of Heterocyclic Compounds; Dec2005, Vol. 41 Issue 12, p1447
Data on the synthesis, complexing ability, practical applications, and biological activity of dibenzotetraazamacroheterocycles of the azacrown ether, amide, and azomethinedibenzotetraazacycloalkane types and also dibenzotetraazamacroheterocycles containing amide and azomethine fragments are...
- Collective behaviour of crown channels.
Vijayvergiya, Viksita; Bose, Debasish; Ghosh, Paramita; Ghosh, Subhendu // European Biophysics Journal; 2003, Vol. 32 Issue 8, p724
Collective behaviour of a crown ether channel, bis[(benzo-15-crown-5)-15-yl methyl] pimelate, in a planar lipid bilayer membrane has been studied through electrophysiological methods. A characteristic feature of these channels is their sequential opening, indicated by a uniform stepwise increase...
- Effect of cyclic benzo-12-crown-4 polyether on copper electrodepsosition from sulfate aqueous ethanol baths.
Kuznetsov, V. V.; Skibina, L. M.; Geshel', S. V. // Protection of Metals; May2006, Vol. 42 Issue 3, p253
It is found that the effectiveness of crown ether (with benzo-12-crown-4 as an example) is a function of the composition of the water-ethanol solvent and the bulk and surface concentration of sulfate anions. An increase in the adsorbability of sulfate anions at Cu in the presence of the crown...
- Coprecipitation of Trace Amounts of 137Cs and 85Sr with [Na(18-Crown-6]BPh4 from Neutral and Alkaline Solutions.
Kulyukhin, S.; Konovalova, N.; Rumer, I.; Kamenskaya, A.; Mikheev, N. // Radiochemistry; May2005, Vol. 47 Issue 3, p284
Coprecipitation of 137Cs and 85Sr with [Na(18-crown-6]BPh4 solid phase from aqueous, aqueous-ethanolic, and alkaline solutions is studied. 137Cs and 85Sr cocrystallize with [Na(18-crown-6]BPh4 from aqueous and aqueous-ethanolic solutions. The cocrystallization coefficients D of 137Cs and 85Sr...
- Formation and Decomposition of Potassium Potassides Complexed Crown Ethers in Tetrahydrofuran Solution.
Grobelny, Zbigniew; Stolarzewicz, Andrzej; Szczepanski, Marcin; Sok�l, Maria // Current Organic Chemistry; Aug2008, Vol. 12 Issue 12, p1040
This review systematizes the essential data on alkalide solutions called also alkali metal solutions or blue solutions, i.e. solutions of the salts containing alkali metal anions (M-). It focuses particularly on the formation and decomposition of potassium potassides as well as on the...
- Application of Crown Ethers as Buffer Additives in Capillary Electrophoresis.
Elbashir, Abdalla A.; Aboul-Enein, Hassan Y. // Current Pharmaceutical Analysis; May2010, Vol. 6 Issue 2, p101
This paper provides an overview of the applications of crown ethers as buffer additive in capillary electrophoresis. The applications area can be categorized into the separation of inorganic cations; chiral separation and separation of organic compounds include positional isomers. The use of...
- Composite chemosensor materials based on polymer matrices with crown ether derivatives.
Zaitsev, I. S.; Tsar'kova, M. S.; Timonin, A. N.; Zaitsev, S. Yu.; Sazonov, S. K.; Vedernikov, A. I.; Gromov, S. P. // International Polymer Science & Technology; 2012, Vol. 39 Issue 6, p59
Composite materials, consisting of a polymer matrix and a crown ether derivative immobilised in it, and possessing photochromic properties, have been obtained and investigated. The possibility of using them to detect mercury(II) cations has been shown.
- Synthesis of Unconventional Materials Using Chitosan and Crown Ether for Selective Removal of Precious Metal Ions.
Dhakal, Rabindra Prasad; Oshima, Tatsuya; Baba, Yoshinari // World Academy of Science, Engineering & Technology; Aug2009, Issue 32, p204
The polyfunctional and highly reactive bio-polymer, the chitosan was first regioselectively converted into dialkylated chitosan using dimsyl anionic solution(NaH in DMSO) and bromodecane after protecting amino groups by phthalic anhydride. The dibenzo-18-crown-6-ether, on the other hand, was...
- Construction, synthesis and study of new discotic mesogens.
Akopova, O. B. // Journal of Structural Chemistry; Jan2006, Vol. 47 Issue 1, p120
The calculation and analysis of molecular parameters (MPs) has been carried out for five series of triphenylene derivatives and crown ether derivatives (30 molecules) containing chiral or complexing centers. The values of the MP were used to predict possible occurrence of columnar and nematic...
- Solvent Extraction of Sodium Permanganate by Mono-benzo 3m-Crown-m Ethers (m = 5, 6) into 1 ,2-Dichloroethane and Nitrobenzene: a Method which Analyzes the Extraction System with the Polar Diluents.
Kudo, Yoshihiro; Harashima, Kyohei; Katsuta, Shoichi; Takeda, Yasuyuki // International Journal of Chemistry; Feb2011, Vol. 3 Issue 1, p99
Analytical equations were derived for the extraction of univalent metal salts (MA) by crown ethers (L) into polar diluents. Then, NaMnO4 was extracted at 25 Â°C by benzo-15-crown-5 and -18-crown-6 ethers (B15C5 and B18C6) from a water (w)-phase into a 1,2-dichloroethane (DCE)-one. So, the...
- Kinetics of the adsorption of strontium(II) by a novel silica-based 4,4',(5')-di(tert-butylcyclohexano)-18-crown-6 extraction resin in nitric acid medium.
Zhang, A.; Wei, Y.-Z.; Kumagai, M.; Koyama, T. // Journal of Radioanalytical & Nuclear Chemistry; Dec2004, Vol. 262 Issue 3, p739
A new type of silica-based chelating extraction resin, DtBuCH18C6/SiO2-P, was prepared by impregnating a crown ether derivative, 4,4Â¢,(5Â¢)-di(tert-butylcyclohexano)-18-crown-6 (DtBuCH18C6), into the porous silica/polymer composite particles (SiO2-P). The adsorption of Sr(II) and some other...
- Hydrogen peroxide oxidative desulfurization of model diesel mixtures using azacrown ethers.
Rakhmanov, E.; Baranova, S.; Wang, Zixiao; Tarakanova, A.; Kardashev, S.; Akopyan, A.; Naranov, E.; Oshchepkov, M.; Anisimov, A. // Petroleum Chemistry; Jul2014, Vol. 54 Issue 4, p316
Hydrogen peroxide oxidative desulfurization of model diesel fuel mixtures in the presence of azacrown ethers and their complexes with niobium pentachloride at 40-80Â°C has been studied. It has been found that the use of complexes of azacrown ethers with NbCl leads to a decrease in the total...
- Synthesis, X-ray crystal structure, and solid-state [sup 13] C NMR study of tris(9-crown-3)triphenylene.
Buchanan, Gerald W; Rastegar, Majid F; Yap, Glenn PA // Canadian Journal of Chemistry; Feb2001, Vol. 79 Issue 2, p195
Benzo-9-crown-3 ether trimerizes in the presence of FeCl[sub 3] and aqueous H[sub 2] SO[sub 4] to produce tris(9-crown-3)triphenylene in 25.4 yield. This compound crystallizes in the monoclinic P2[sub 1] /c space group: a = 13.759(2) Ã…, b = 13.318(2) Ã…, c = 13.399(2) Ã…, Î² =...
- Copper Electroplating from Sulfate Electrolytes Containing Crown Ethers.
Kuznetsov, V.V.; Skibina, L.M.; Geshel', S.V. // Protection of Metals; Mar/Apr2003, Vol. 39 Issue 2, p145
It is found that, an excess of copper ions inhibits electroplating due to adsorption of electroactive substance resulting from the interaction of discharging metal ions with crown ester (CE) additive in the surface layer. When the crown ester is in excess, preceding dissociation of complexes...
- Discussion on complexation reactions between dicyclohexyl-18-crown-6 (DCH18C6) with Na+, K+, Cs+, Rb+, and Tl+ metal cations in acetonitrile-water binary mixtures.
Soorgi, M. H.; Rounaghi, G. H.; Kazemi, M. S. // Russian Journal of General Chemistry; Oct2008, Vol. 78 Issue 10, p1866
The complex formation between Na+, K+, Cs+, Rb+ and Tl+ metal cations with macrocyclic ligand, dicyclohexyl-18-crown-6 (DCH18C6) was studied in acetonitrile-water (AN-H2O) binary systems at different temperatures using conductometric method. DCH18C6 forms 1:1 complexes with these metal cations....
- Synthesis, complex-formation, and extracting ability of new derivatives of dithia-13(16)-crown-4(5) ethers.
Tulyakova, E. V.; Rakhmanov, E. V.; Lukovskaya, E. V.; Fedorova, O. A.; Abramov, A. A.; Khoroshutin, A. V.; Bobylyova, A. A.; Anisimov, A. V. // Chemistry of Heterocyclic Compounds; Feb2006, Vol. 42 Issue 2, p206
Various methods of synthesizing functional derivatives of dithia-13(16)-crown-4(5) ethers are proposed. Complex-formation of the obtained compounds with Ag+ and Pb2+ ions has been studied using 1H NMR. A radiometric method was used to investigate the extracting ability of substituted...
- Use of open-cell resilient polyurethane foam loaded with crown ether for the preconcentration of uranium from aqueous solutions.
Abou-Mesalam, M. M.; El-Naggar, I. M.; Abdel-Hai, M. S.; El-Shahawi, M. S. // Journal of Radioanalytical & Nuclear Chemistry; Nov2003, Vol. 258 Issue 3, p619
The preconcentration of uranium from aqueous solutions on open-cell resilient polyurethane foams (PUF) impregnated with crown ether as an organic extractant in different conditions was investigated. The data showed that 50 minutes is a sufficient time to attain equilibrium with a maximum...
- Synergistic extraction of Ce(III), Eu(III) and Tm(III) with a mixture of picrolonic acid and benzo-15-crown-5 in chloroform.
Rehman, Habib-ur-; Ali, Akbar; Anwar, Jamil; Yawar, Wasim // Journal of Radioanalytical & Nuclear Chemistry; Feb2006, Vol. 267 Issue 2, p421
The synergistic mixture comprising picrolonic acid (HPA) and benzo-15-crown-5 (B15C5) in chloroform has been used for the extraction of Ce(III), Eu(III) and Tm(III) as representatives of lanthanide(III) ions from pH 1-2 solutions having ionic strength of 0.1 mol. dm-3(K+/H+, Cl-). The...
- Radiation chemical synthesis of polyethylene oxide hydrogel containing DCH18C6 crown ether: A new approach.
Zakurdaeva, O. A.; Nesterov, S. V.; Feldman, V. I. // Journal of Radioanalytical & Nuclear Chemistry; Aug2004, Vol. 261 Issue 2, p245
Polyethylene oxide hydrogels containing physically immobilized dicyclohexano-18-crown-6 were prepared by radiation chemical synthesis. Doses of gel formation were found to depend on the molecular weight of the polyethylene oxide and were about 20 and 4 kGy for Mw of 105 and 3.106, respectively....
- DFT study of glucose based glycolipid crown ethers and their complexes with alkali metal cations Na and K.
Nguan, Hockseng; Ahmadi, Sara; Hashim, Rauzah // Journal of Molecular Modeling; Dec2012, Vol. 18 Issue 12, p5041
A theoretical study of a series of five glucose based glycolipid crown ethers and their complexes with Na and K was performed using the density functional theory with B3LYP/6-31 G* to obtain the optimized geometrical structures and electronic properties. The local nucleophilicity of the five...
- A pentagonal cyanostar macrocycle with cyanostilbene CH donors binds anions and forms dialkylphosphate rotaxanes.
Lee, Semin; Chen, Chun-Hsing; Flood, Amar H. // Nature Chemistry; Aug2013, Vol. 5 Issue 8, p704
Since the discovery of crown ethers, macrocycles have been recognized as powerful platforms for supramolecular chemistry. Although their numbers and variations are now legion, macrocycles that are simple to make using high-yielding reactions in one pot and on the multigram scale are rare. Here...
- Synthesis, reactions, applications, and biological activity of diethanolamine and its derivatives.
Yar, M.; Mushtaq, N.; Afzal, S. // Russian Journal of Organic Chemistry; Jul2013, Vol. 49 Issue 7, p949
The review considers recent advances in using diethanolamine (DEA) in the synthesis of amides, polymerization reactions, and synthesis of heterocycles, crown ethers, Mannich bases, and ionic liquids. Biological activity of DEA and its derivatives is also reviewed.
- DFT modeling on the suitable crown ether architecture for complexation with Cs and Sr metal ions.
Boda, Anil; Ali, Sk. Musharaf; Shenoi, Madhav R. K.; Rao, Hanmanth; Ghosh, Sandip K. // Journal of Molecular Modeling; May2011, Vol. 17 Issue 5, p1091
Crown ether architectures were explored for the inclusion of Cs and Sr ions within nano-cavity of macrocyclic crown ethers using density functional theory (DFT) modeling. The modeling was undertaken to gain insight into the mechanism of the complexation of Cs and Sr ion with this ligand...
- Influence of the structure of organophosphorus substituents on the extraction ability of diphosphorylated crown ethers.
Yakshin, V. V.; Vilkova, O. M.; Tananaev, I. G.; Kal’chenko, V. I.; Tsivadze, A. Yu.; Myasoedov, B. F. // Radiochemistry; Nov2008, Vol. 50 Issue 6, p616
Extraction properties of lariat crown ethers were studied. Dibenzo-substituted crown ethers of a new class, with electron-donor side phosphoryl groups -P(O)R2 (R = iso-C3H7O, n-C4H9O, C6H5), were proposed as extracting agents. The oxygen atoms of the phosphoryl groups form additional bonds with...
- Selectivity of bis[ n-butyl(hydroxyl)phosphoryl]dibenzo crown ether endoreceptors in metal extraction from nitric acid solutions.
Yakshin, V. V.; Vilkova, O. M.; Tananaev, I. G.; Kal’chenko, V. I.; Tsivadze, A. Yu.; Myasoedov, B. F. // Radiochemistry; Nov2008, Vol. 50 Issue 6, p612
Diphosphorylated dibenzo crown ethers with 4,4â€²(5â€²)-bis[ n-butyl(hydroxy)]phosphoryl substituents at the benzene rings of dibenzo-18-crown-6 ( I), dibenzo-21-crown-7 ( II), and dibenzo-24-crown-8 ( III) were prepared and studied with the aim of developing new highly effective and...
- Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) as Donor Ligands in Organotin(IV) Derivatives: Synthesis, Spectroscopic Characterization and Biological Applications.
Shahzadi, Saira; Shahid, Khadija; Ali, Saqib; Mazhar, Mohammad; Badshah, Amin; Ahmed, Ejaz; Malik, Abdul // Turkish Journal of Chemistry; 2005, Vol. 29 Issue 3, p273
Some new di- and tri-organotin(IV) derivatives of 4 different non-steroidal anti-inflammatory drugs (NSAIDs) with the general formulae R2SnL2 and R3SnL (where R = n-C8H17 and C6H5CH2) and L = 2-[(2,3-dimethylphenyl)amino]benzoic acid 2-(2-fluoro-4-biphenyl)propionic acid, 2-(4-isobutylphenyl)...
- A novel crown ether generation containing the pyrilium heteroaromatic cation – Synthesis, characterization, and solid-phase 13C NMR.
Moghimi, Abolghasem; Rastegar, Majid Faal; Ghandi, Mehdi // Canadian Journal of Chemistry; Dec2004, Vol. 82 Issue 12, p1716
The synthesis and structural characterization of two members, 5 and 6, of a novel generation of crown ethers containing the pyrilium cation are reported. These two compounds contain two and three benzo-9-crown-3 (B9C3) units, respectively, connected to the 2 and 6 or 2, 4, and 6 positions of a...
- Effect of crown ether ring size on binding and fluorescence response to saxitoxin in anthracylmethyl monoazacrown ether chemosensors.
Hua Mao; Thorne, John B.; Pharr, Jennifer S.; Gawley, Robert E. // Canadian Journal of Chemistry; Oct2006, Vol. 84 Issue 10, p1273
Convenient macrocyclization synthetic routes for the preparation of different-sized monoaza anthracylmethyl crown ether chemosensors (15-crown-5, 18-crown-6, 21-crown-7, 24-crown-8, and 27-crown-9) are described. Evaluation of these crowns as chemosensors for saxitoxin revealed that the larger...
- Host-guest complexes of crown ethers with HN-proton-donor molecules.
Wang, Wen-Jwu; Ganin, E. V. // Russian Journal of General Chemistry; Dec2004, Vol. 74 Issue 12, p1918
Crown ethers were reacted with HN-proton-donor molecules to obtain crystalline molecular host-guest complexes. It was found that complexes with crown ethers of different structure are formed, depending on the linear dimensions and mode of steric shielding of active centers of the proton-donor...
- New Synthesis of Formylbenzoazacrown Ethers.
Dmitrieva, S. N.; Tikhonova, O. V.; Gromov, S. P. // Russian Journal of Organic Chemistry; Sep2005, Vol. 41 Issue 9, p1387
A new procedure has been developed for the synthesis of formyl-substituted benzoazacrown ethers via cyclization of halogen derivatives of aza podands by the action of sodium hydride.
- Rotaxanes and pseudorotaxanes with threads containing viologen units.
Deska, Malgorzata; Kozlowska, Jolanta; Sliwa, Wanda // ARKIVOC: Online Journal of Organic Chemistry; 2013, p66
In the present review rotaxanes and pseudorotaxanes with threads containing viologen units are described. First the rotaxanes and pseudorotaxanes in which the crown ether serves as a ring are presented, they are followed by rotaxanes and pseudorotaxanes containing the crown-based cryptand as a...
- Chiral lariat ethers based on spontaneously resolved 3-(2-cyanophenoxy)propane-1,2-diol.
Fayzullin, R.; Bredikhina, Z.; Sharafutdinova, D.; Bazanova, O.; Bredikhin, A. // Russian Journal of Organic Chemistry; Apr2014, Vol. 50 Issue 4, p611
The article discusses a study on the chiral lariat ethers based on spontaneously resolved 3-(2-Cyanophenoxy)propane-1,2-diol. The study has showed formation of supramolecular complexes by crown ether (R)-III and enantiomers of 1-phenylethanamine hydrochloride IV-HCl. Also offered is a synthesis...
- Determination of ion-pair formation constants of univalent metal-crown ether complex ions with anions in water using ion-selective electrodes: application of modified determination methods to several salts.
Kudo, Yoshihiro; Wakasa, Masaomi; Ito, Tomomi; Usami, Jun; Katsuta, Shoichi; Takeda, Yasuyuki // Analytical & Bioanalytical Chemistry; Jan2005, Vol. 381 Issue 2, p456
Ion-pair formation constants (mol-1 dm3 unit),KMX for a univalent metal salt (MX) andKMLX for its ion-pair complex (ML+X-) with a crown ether (L) in water, were determined at various ionic strengths (I) and 25Â°C by potentiometry with ion-selective electrodes for MX=NaPic, NaMnO4, NaBPh4,...
- SOLUBILIZATION AND UTILIZATION OF CROWN ETHER/IONIC DYE COMPLEXES.
Kudo, Yoshihiro; Wakasa, Masaomi; Ito, Tomomi; Usami, Jun; Katsuta, Shoichi; Takeda, Yasuyuki // Book of Papers, National Technical Conference of AATCC; 1982, p22
Crown ethers are cyclopolymers based on ethylene oxide units. They have the ability to strongly complex cations via ionic co-ordination through the unshared electron pairs on the oxygen atoms. The ligand 18-crown-6 was utilized to solubilize C.I. Acid Yellow 36, C.I. Acid Red 151 and C.I. Acid...
- Theoretical studies of actinyl crown ether inclusion complexes.
Martin, Richard L.; Jeffrey Hay, P.; Schreckenbach, Georg // AIP Conference Proceedings; 2000, Vol. 532 Issue 1, p392
Clark et al. recently reported the synthesis of the NpO[sub 2][sup +]ion encapsulated by the 18-crown-6 ligand. The [NpO[sub 2](18-crown-6)]ClO[sub 4] salt was characterized crystallographically and shown to have six approximately coplanar crown ether oxygen atoms coordinated to a central...