TITLE

‘‘Gentle recoil’’ synthesis of free-radical clusters via unimolecular photolysis of closed shell complexes

AUTHOR(S)
Mackenzie, S. R.; Votava, O.; Fair, J. R.; Nesbitt, D. J.
PUB. DATE
December 1996
SOURCE
Journal of Chemical Physics;12/22/1996, Vol. 105 Issue 24, p11360
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
We describe a novel mechanism for efficient generation of open shell free-radical complexes via UV photolysis of the corresponding closed shell precursors. Ar-SH and Ar[SUB2]-SH are detected following 248 nm excitation of Ar-H[SUB2]S and Ar[SUB2]-H[SUB2]S. Of particular dynamical interest are the nonfragmentary channels in which no Ar atoms are ejected.
ACCESSION #
9815304

 

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