TITLE

Unususal reaction of trifluoromethanesulfonamide with diallyl sulfide

AUTHOR(S)
Moskalik, M.; Astakhova, V.; Shainyan, B.
PUB. DATE
May 2013
SOURCE
Russian Journal of Organic Chemistry;May2013, Vol. 49 Issue 5, p761
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The article describes the chemical synthesis between triflamide and diallyl sulfide in acetonitrile in the oxidative system of t-BuOCl. The synthesis is influenced by two π bonds carbon=carbon (C=C) and atom in sulfur and resulted to two σ-bonds sulfur-nitrogen (S-N), N,N′-(diprop-2-en-1-yl-λ4-sulfanediyl)bis(1,1,1-trifluoromethanesulfonamide). Quantum-chemical calculations were performed with geometry optimization.
ACCESSION #
88060425

 

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