Fe-catalyzed synthesis of (4 E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm ( Keiferia lycopersicella)

Shakhmaev, R.; Sunagatullina, A.; Zorin, V.
May 2013
Russian Journal of Organic Chemistry;May2013, Vol. 49 Issue 5, p669
Academic Journal
Starting with industrially available 1,3-dichloropropene a stereoselective process was developed for the preparation of (4 E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm ( Keiferia lycopersicella) using in the key stage the Fe-catalyzed cross-coupling of ethyl (4 E)-5-chloropent-4-enoate with octylmagnesium bromide.


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