TITLE

Magnetic circular dichroism of Na3Nd(ODA)3·2NaClO4·6H2O

AUTHOR(S)
Fluyt, L.; Couwenberg, I.; Lambaerts, H.; Binnemans, K.; Görller-Walrand, C.; Reid, M. F.
PUB. DATE
October 1996
SOURCE
Journal of Chemical Physics;10/15/1996, Vol. 105 Issue 15, p6117
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
This paper emphasizes the complementarity between optical and magneto-optical measurements on f elements. The magnetic circular dichroism, circular dichroism, and polarized absorption spectra of Na3Nd(ODA)3·2NaClO4·6H2O (NdODA), have been recorded at 4.2 K between 5000 and 30 000 cm-1. The electric dipole contributions to the f–f transitions are analyzed using a parametric model which contains 12 parameters which are determined by fitting the calculated to the empirical dipole strengths of 50 α and 16 π polarized absorption lines. The reliability of these intensity parameters is tested by simulating the more sensitive magneto-optical (magnetic circular dichroism) and chiroptical (circular dichroism) spectra. © 1996 American Institute of Physics.
ACCESSION #
7649563

 

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