TITLE

Polarization effects in time resolved incoherent anti-Stokes Raman spectroscopy

AUTHOR(S)
Hofmann, M.; Zürl, R.; Graener, H.
PUB. DATE
October 1996
SOURCE
Journal of Chemical Physics;10/15/1996, Vol. 105 Issue 15, p6141
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Recently the anti-Stokes spectroscopy after strong vibrational excitation via resonant absorption was rediscovered, for the study of population relaxation dynamics. A closer theoretical inspection of this experimental approach reveals that properly chosen polarization conditions allow the study of molecular reorientational motion. Furthermore the sign of a/γ (the invariants of the Raman polarizability tensor) can be determined. Experimental data for chlorinated alkanes will be presented. © 1996 American Institute of Physics.
ACCESSION #
7649561

 

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