TITLE

Three-spin interaction in liquid state nuclear magnetic resonance

AUTHOR(S)
Brüschweiler, R.
PUB. DATE
October 1996
SOURCE
Journal of Chemical Physics;10/15/1996, Vol. 105 Issue 15, p6164
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The imaginary part of the magnetic dipole–dipole cross correlation spectral density in spin 1/2 systems generates a novel type of three-spin Hamiltonian with terms IizIjzIkz, IizIjxIkx, and IizIjyIky and permutations in the spin labels i, j, k. These terms cause asymmetric positions of the spin multiplet components, which could not be explained by scalar J-coupling and chemical shift terms. © 1996 American Institute of Physics.
ACCESSION #
7649559

 

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