TITLE

Determination of the structure of HCl BF3

AUTHOR(S)
LoBue, James M.; Rice, Jane K.; Blake, Thomas A.; Novick, Stewart E.
PUB. DATE
October 1986
SOURCE
Journal of Chemical Physics;10/15/1986, Vol. 85 Issue 8, p4261
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The structure of the weakly bound complex HCl BF3 has been determined by molecular beam electric resonance spectroscopy. The molecule is a near prolate symmetric top with the chlorine atom 3.17 Å above the boron atom, on or very near the BF3 threefold axis. The B–Cl–H angle is close to 90°. The spectroscopic constants for the H35Cl11BF3 isotope are (B+C)/2=1774.117(4) MHz, DJ=5.6(5) kHz, eqQa(35Cl)=+25.761(8) MHz, eqQa(11B)=+2.672(25) MHz, and μa=0.484(5)D.
ACCESSION #
7645553

 

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