TITLE

Solid-state kinetics and gas-phase prediction of 1,4-bis(trimethylsilyl)benzene

AUTHOR(S)
Selvakumar, J.; Sathiyamoorthy, D.; Nagaraja, K.
PUB. DATE
July 2012
SOURCE
Journal of Thermal Analysis & Calorimetry;Jul2012, Vol. 109 Issue 1, p113
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The solid-state kinetics and gas-phase predictions of the 1,4-bis(trimethylsilyl)benzene (TMSB) are visualized by utilizing thermogravimetric and mass spectral data. The statistical analyses and reduced time plots of zero order (F0) and Avrami-Erofeev (A2) nucleation and growth models provides the best fit to experimental data for isothermal evaporation process for TMSB. The activation energy for non-isothermal evaporation processes of TMSB is calculated using isoconversional methods. The molecular structure and energetics of the predicted gas phase molecules and species in chemical vapor deposition process are investigated using semi-empirical quantum chemical calculations.
ACCESSION #
76447189

 

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