Measurement of the state-specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV

Xu, Hao; Shafer-Ray, Neil E.; Merkt, Frédéric; Hughes, Daniel J.; Springer, Michael; Tuckett, Richard P.; Zare, Richard N.
September 1995
Journal of Chemical Physics;9/22/1995, Vol. 103 Issue 12, p5157
Academic Journal
HI and D2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm initiates the H+D2 reaction. The HD(v=4,J′=3) velocity distribution is determined by analyzing the time-of-flight profile of HD+ ions produced by delayed pulsed field ionization of long-lived Rydberg states. The angular distribution is deduced using the law of cosines (photoloc technique). © 1995 American Institute of Physics.


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