TITLE

Extreme metastability in Ar–HCl (v=1) and Ar–DF (v=1)

AUTHOR(S)
Oudejans, L.; Nauta, K.; Miller, R. E.
PUB. DATE
December 1996
SOURCE
Journal of Chemical Physics;12/15/1996, Vol. 105 Issue 23, p10410
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
High resolution optothermal spectra have been obtained for the Ar–HCl and Ar–DF complexes which conclusively show that they do not dissociate on H/D–X vibrational excitation. The observed linewidths place a lower limit on the lifetimes of 500 ns, while time-of-flight considerations indicate that the lifetimes are in excess of 0.4 ms. Stark spectra are also reported, which result in the determination of the (v=1) excited state dipole moments of these complexes. © 1996 American Institute of Physics.
ACCESSION #
7629824

 

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