TITLE

A classical path theory of collisional redistribution in CaHe spin-changing energy transfer collisions

AUTHOR(S)
Ananthamurthy, S.; Sando, K. M.; Kleiber, P. D.
PUB. DATE
December 1994
SOURCE
Journal of Chemical Physics;12/15/1994, Vol. 101 Issue 12, p10485
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
We have applied a semiclassical (classical path quantum close-coupling) nonadiabatic theory of collisional redistribution to model Ca–He spin-changing energy transfer collisions. The theory predicts the total far wing absorption and final state resolved action spectra. The semiclassical model predictions are in excellent agreement with full quantum mechanical close-coupling calculations [J. Chem. Phys. 95, 5861 (1991)] and both are in good accord with the experimental observations. © 1994 American Institute of Physics.
ACCESSION #
7629616

 

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