Reaction path analysis of the rate of unimolecular isomerization

Jang, Soonmin; Rice, Stuart A.
December 1993
Journal of Chemical Physics;12/15/1993, Vol. 99 Issue 12, p9585
Academic Journal
We show that a reaction path Hamiltonian can be used, with the basic concepts of the Davis–Gray analysis of unimolecular reaction rate, to generate an accurate description of the dynamics of a model isomerization reaction.


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