TITLE

Theoretical study of properties of H- and NH2- complexes with neutral ammonia solvent molecules

AUTHOR(S)
Roszak, S.
PUB. DATE
November 1996
SOURCE
Journal of Chemical Physics;11/1/1996, Vol. 105 Issue 17, p7569
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The experimental results from photoelectron spectroscopy yielding detailed information on interactions of H- and NH-2 with one and two molecules of NH3 are supplemented by theoretical studies. The structure of complex anions involved has been determined and the nature of their interactions has been discussed. Electron affinities, dissociation energies, and basicity of H-(NH3)n and NH-2(NH3)n (n=1,2) anions have been calculated for theoretically determined structures. The excellent agreement between experimental and theoretical results confirms conclusions derived from experimental studies. A recently proposed complete basis set method has been proven to be a useful tool to study weak molecular complexes. © 1996 American Institute of Physics.
ACCESSION #
7619959

 

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