TITLE

High pressure transformations of NaOH

AUTHOR(S)
Beck, Horst P.; Lederer, Gunda
PUB. DATE
May 1993
SOURCE
Journal of Chemical Physics;5/1/1993, Vol. 98 Issue 9, p7289
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The structures of two high pressure modifications of NaOH have been determined by in situ x-ray measurements with a diamond anvil cell. Thermodynamic data for the transformation are derived from the P,T diagram. The structures are discussed and especially the influence of the H atoms on characteristic deformations. The compressibility of α-NaOH shows an anomaly, which can be explained by a continuous transformation to yet another new modification, which is isotypic with the low-temperature form of NaOD.
ACCESSION #
7618662

 

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