# Auger electron spectroscopy of molecules: Theory for spin polarization following photoabsorption

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We use one color, resonant two photon absorption to ionize a skimmed atomic beam of V formed by laser vaporization of a target rod in the throat of a pulsed nozzle. The resulting time-of-flight photoelectron spectra resolve the 3d4(5D), 3d34s(5F), and 3d34s(3F) electronic terms and the...