On the photoelectron spectrum of AgO[sup -]

Andrews, Django H.; Gianola, Adam J.; Lineberger, W. Carl
August 2002
Journal of Chemical Physics;8/22/2002, Vol. 117 Issue 8, p4074
Academic Journal
The 364 nm negative ion photoelectron spectrum of AgO[sup -] is reported. Transitions to the A [sup 2]Σ[sup +] state and the X [sup 2]Π[sub 1/2] and X [sup 2]Π[sub 3/2] spin–orbit states of AgO are observed. The electronic ground state of AgO[sup -] is found to have a vibrational frequency of 497 (20) cm[sup -1] and an equilibrium bond length of 1.935 (15) Å. The electron affinity of AgO is found to be 1.654 (2) eV. © 2002 American Institute of Physics.


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