TITLE

Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent

AUTHOR(S)
Sayyed-Alangi, S. Zahra; Sajjadi-Ghotbabadi, H.; Baei, Mohammed T.; Naderi, Sahar
PUB. DATE
April 2011
SOURCE
E-Journal of Chemistry;2011, Vol. 8 Issue 2, p815
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Morpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions. Moreover, it is inert towards aldehydes, ketons, oximes, thiols, sulfids, phenols, pyrans, trimethylsilanes, malonates and thioacetamides. The durability, reaction rate, ease of filtration and efficiency of MFC are considerably increased upon its absorption on silica gel.
ACCESSION #
62086040

 

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