TITLE

Oxidation of Methionine by Tripropylammonium Fluorochromate-A Kinetic and Mechanistic Study

AUTHOR(S)
Mansoor, S. Sheik
PUB. DATE
April 2011
SOURCE
E-Journal of Chemistry;2011, Vol. 8 Issue 2, p643
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The kinetics of oxidation of methionine (Met) by tripropylammonium fluorochromate (TriPAFC) has been studied in the presence of chloroacetic acid in aqueous acetic acid medium. The reaction is first order with respect to methionine, TriPAFC and acid. The reaction rate has been determined at different temperatures and activation parameters calculated. With an increase in the amount of acetic acid in its aqueous mixture, the rate increases. The reaction does not induce polymerization of acrylonitrile. A suitable mechanism has been proposed.
ACCESSION #
62086016

 

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