TITLE

Nuclear motion and symmetry breaking of core-excited polyatomic molecules—anisotropic fragmentation of CF[sub 4] following F 1s photoabsorption

AUTHOR(S)
Ueda, K.; Muramatsu, Y.; Shimizu, Y.; Chiba, H.; Amano, K.; Sato, Y.; Nakamatsu, H.
PUB. DATE
February 2000
SOURCE
AIP Conference Proceedings;2000, Vol. 500 Issue 1, p223
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Angle-resolved ion yield spectroscopy revealed that ionic fragmentation of a T[sub d] symmetry molecule CF[sub 4] is anisotropic following F 1s photoabsorption. The nuclear motion in the Auger-final state resulting in this anisotropic fragmentation is a consequence of asymmetric nuclear motion or symmetry breaking in the core-excited state, caused by vibronic coupling. © 2000 American Institute of Physics.
ACCESSION #
6029887

 

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