TITLE

[CoCl(TPPyP)], a novel bifunctional catalyst for the coupling reaction of carbon dioxide and propylene oxide

AUTHOR(S)
Ren, Tiegang; Li, Weijie; Bu, Zhanwei; Yang, Lirong; Wang, Zhiqiang
PUB. DATE
July 2010
SOURCE
Journal of Chemical Research;Jul2010, Vol. 34 Issue 7, p361
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
A novel bifunctional catalyst chloro[meso-tetrakis(1-phenylpyrazol-4-yl)porphyrin] cobalt(III), [CoCl(TPPyP)], has been prepared and used to catalyse the synthesis of propylene carbonate from carbon dioxide and propylene oxide under mild conditions. Propylene carbonate was obtained with a yield of 25.2% at 100 �C in the absence of co-catalyst. A reaction mechanism is proposed.
ACCESSION #
54001627

 

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