TITLE

Cooperative enhancement of TPA in cruciform double-chain DSB derivation: a femtosecond transient absorption spectra study

AUTHOR(S)
He, X.; Wang, Y.; Yang, Z.; Ma, Y.; Yang, Y.
PUB. DATE
September 2010
SOURCE
Applied Physics B: Lasers & Optics;Sep2010, Vol. 100 Issue 4, p773
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Femtosecond time-resolved transient absorption (TA) spectra study was adopted to study the mechanism of the cooperative enhancement of two-photon absorption (TPA) cross section from the linear structure 1,4-di(4'-N,N-diphenylaminostyryl)benzene (DPA-DSB) to its cruciform double-chain dimer DPA-TSB. The results suggested that a non-emissive intramolecular charge-transfer (ICT) state, ICT�, was present upon excitation in the dimer, which was absent in the monomer. The existence of this non-emissive state, indicating the enhancement of the intramolecular charge-transfer of the dimer, should be the reason for the cooperative enhancement of the TPA cross section of the dimer compared to the monomer.
ACCESSION #
53361486

 

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