Ultraviolet–visible near-field microscopy of phase-separated blends of polyfluorene-based conjugated semiconductors

Stevenson, R.; Riehn, R.; Milner, R. G.; Richards, D.; Moons, E.; Kang, D.-J.; Blamire, M.; Morgado, J.; Cacialli, F.
August 2001
Applied Physics Letters;8/6/2001, Vol. 79 Issue 6
Academic Journal
We have used fluorescence scanning near-field microscopy to characterize polymer blends for electroluminescent applications, and thereby identify compositional nonhomogeneities. In particular, we have focused on the binary system constituted by poly(9,9′-dioctylfluorenealt-benzothiadiazole) and poly(9,9′-dioctylfluorene) (PFO), known to give efficiencies of up to 22 cd/A in light-emitting devices with suitable electrodes. Our primary aim was the assignment of the morphological features revealed in shear-force and atomic-force images of spin-coated films, and suggestive of phase separation on a 300-nm-length scale. From analysis of the fluorescence images (325 and 488 nm excitation), and quantitative correlation of optical and topographic data, we identify the raised features with PFO-rich regions. However, the limited variation in fluorescence intensity reveals a high extent of mixing within each phase on the length scale accessible in our experiment, approximately 100 nm for our focused-ion-beam-processed probe apertures. © 2001 American Institute of Physics.


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