TITLE

Cationic ordering control of magnetization in Sr[sub 2]FeMoO[sub 6] double perovskite

AUTHOR(S)
Balcells, Ll.; Navarro, J.; Bibes, M.; Roig, A.; Martínez, B.; Fontcuberta, J.
PUB. DATE
February 2001
SOURCE
Applied Physics Letters;2/5/2001, Vol. 78 Issue 6, p781
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The role of the synthesis conditions on the cationic Fe/Mo ordering in Sr[sub 2]FeMoO[sub 6] double perovskite is addressed. It is shown that this ordering can be controlled and varied systematically. The Fe/Mo ordering has a profound impact on the saturation magnetization of the material. Using the appropriate synthesis protocol a value of 3.7 μ[sub B] has been obtained. Mo¨ssbauer analysis reveals the existence of two distinguishable Fe sites and a charge density at the Fe[sup m+] ions significantly larger than 3d[sup 5] suggesting a Fe contribution to the spin-down conduction band. The implications of these findings for the synthesis of Sr[sub 2]FeMoO[sub 6] having optimal magnetoresistance response are discussed. © 2001 American Institute of Physics.
ACCESSION #
4710299

 

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