TITLE

Biolubricant induced phase inversion and superhydrophobicity in rubber-toughened biopolymer/organoclay nanocomposites

AUTHOR(S)
Bayer, Ilker S.; Steele, Adam; Martorana, Philip; Loth, Eric; Robinson, Scott J.; Stevenson, Darren
PUB. DATE
August 2009
SOURCE
Applied Physics Letters;8/10/2009, Vol. 95 Issue 6, p063702
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
We present a simple technique to fabricate rubber-toughened biopolymer/organoclay nanocomposite coatings with highly water repellent surface wetting characteristics and strong adhesion to metal surfaces. The technique combines the principles of phase inversion and atomization of multicomponent polymer/organoclay suspensions containing a biolubricant as the nonsolvent. The biolubricant was a blend of cyclomethicone/dimethiconol oil with fruit kernel oils. The ternary system of cellulose nitrate/solvent/biolubricant was blended with rubber dispersed organoclay nanofluids. Natural, synthetic, and fluoroacrylic latex rubbers were used for the purpose. Self-cleaning superhydrophobic coatings were obtained from synthetic and fluoroacrylic rubbers whereas natural rubber containing formulations resulted in sticky superhydrophobic coatings.
ACCESSION #
43720406

 

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