# Gibbs free-energy difference between the glass and crystalline phases of a Ni-Zr alloy

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The chemical potential of a binary solution is calculated using the Gibbs free energy method. With the aid of certain assumptions on the microscopic structure of the solution, the wellknown expression is derived for a simple solution. It is shown that the empirical interaction parameter is...

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An apparent discrepancy in the data for the Gibbs free energy change as a function of temperature at different pHs, originally published by Brandts in 1965 and repeated by Brandts and Hunt in 1967 with an unexplained change in sign, has lead to close to 40 years of misguided thinking in...

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The free-energy change in a system represented by an empirical energy function, when calculated by thermodynamic integration from the initial to the final state, can be expressed as a sum of "free-energy components," that correspond to contributions from different energy terms or different parts...

- Extension of microscopic theory of nucleation to macroscopic clusters. Kobraei, H. R.; Anderson, B. R. // Journal of Chemical Physics;1/1/1991, Vol. 94 Issue 1, p590
A microscopic model of homogeneous nucleation is extended to apply to macroscopic clusters. The definition used for physical clusters is identical to that of Reiss, Katz, and Cohen, which has also been introduced by Lee, Barker, and Abraham. Practical approximations have been employed to obtain...