Unimolecular dissociation dynamics of highly vibrationally excited DCO (X[sup 2] A'). II

Keller, Hans-Martin; Stumpf, Michael; Schroder, Thomas; Stock, Christoph; Temps, Friedrich; Schinke, Reinhard; Werner, Hans-Joachim; Bauer, Cornelia; Rosmus, Pavel
April 1997
Journal of Chemical Physics;4/1/1997, Vol. 106 Issue 13, p5359
Academic Journal
Presents a theoretical study of the unimolecular dissociation of DCO in the electronic ground state using an ab initio potential energy surface. Agreement of resonance positions and widths with stimulated emission pumping measurements of Stock et al.; Prohibition of a unique assignment of a 1:1:2 stretch-stretch-bend resonance.


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