New statistical mechanical treatment of systems near surfaces. I. Theory and principles

Gujrati, P.D.; Chhajer, Mukesh
April 1997
Journal of Chemical Physics;4/1/1997, Vol. 106 Issue 13, p5599
Academic Journal
Presents a theoretical framework for a statistical mechanical and thermodynamic description of any general inhomogeneous system in the presence of surfaces. Extension of a lattice theory developed for a homogeneous system; Basic elements of the modified tree structure; Achievement of surface free energy and surface entropy.


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