Model study of near-threshold photoionization of large molecules: The effect of vibrational

Thoss, Michael; Domcke, Wolfgang
February 1997
Journal of Chemical Physics;2/22/1997, Vol. 106 Issue 8, p3174
Academic Journal
Investigates the influence of intramolecular vibrational relaxation in large molecules on near-threshold photoabsorption and photoionization processes. Vibrational relaxation that results from coupling of the initially excited modes to a large number of inactive bath modes; Characteristic effects of vibrational relaxation on absorption and ionization spectra.


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