TITLE

Nonlinear effects in dipole solvation. II. Optical spectra and electron transfer activation

AUTHOR(S)
Matyushov, Dmitry V.; Ladanyi, Branka M.
PUB. DATE
August 1997
SOURCE
Journal of Chemical Physics;8/1/1997, Vol. 107 Issue 5, p1375
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Presents a theoretical analysis of the effect of nonlinear dipole solvation on steady-state optical spectra and intramolecular electron transfer (ET) reactions. Solvation nonlinearity attributed to saturation of a dipole liquid produced by the solute dipole; Exploration of perturbation expansion by the treatment over solute-solvent dipolar interaction.
ACCESSION #
4283769

 

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