Measurement of the rotational distribution for the OD product from the reaction

Green, Richard J.; Zare, Richard N.
July 1997
Journal of Chemical Physics;7/15/1997, Vol. 107 Issue 3, p772
Academic Journal
Investigates the state-to-state ion-molecule reaction. Irradiation of slowly flowing mixture of nitrogen and deuterium; Rotational distribution of product measured by recording laser-induced fluorescence spectrum; Case of the reaction with excited ND.


Related Articles

  • Hindered rotation in ion-neutral molecular complexes: The v[sub 1] vibration of... Olkhov, Rouslan V.; Nizkorodov, Sergey A.; Dopfer, Otto // Journal of Chemical Physics;11/22/1997, Vol. 107 Issue 20, p8229 

    Reports on the hindered rotation in ion-neutral molecular complexes. Anomalous rotational constants obtained by fitting the observed line positions to a semirigid Watson A-type Hamiltonian; Use of an atom-diatom hindered rotor Hamiltonian; Vibrational excitation attributed to electrostatic effects.

  • Deduction of low density limit to rate of ter-molecular ion–molecule association from measurements. Bates, David R. // Journal of Chemical Physics;6/1/1986, Vol. 84 Issue 11, p6233 

    The low density limit k0 to the ter-molecular ion–molecular association coefficient is shown to be related through a double integral to X≡k(exp) [M] ( μ/α)1/2, where k (exp) is the measured association coefficient at ambient gas density [M], α is the polarizability of the...

  • Spectroscopic observation of the highest vibrational level of the HD+(2Σ+) molecule. Carrington, Alan; McNab, Iain R.; Montgomerie, Christine A. // Journal of Chemical Physics;9/1/1987, Vol. 87 Issue 5, p3246 

    Spectroscopic observation of the highest vibrational level of HD+(v=21) in its ground electronic state is reported. Calculations of constants from the resolved hyperfine structure allow unambiguous determination of the Fermi contact parameters for the levels 17,1 and 21,0, showing that in the...

  • CH2+ is bent. Graber, T.; Kanter, E. P.; Vager, Z.; Zajfman, D. // Journal of Chemical Physics;5/15/1993, Vol. 98 Issue 10, p7725 

    The Coulomb explosion imaging (CEI) technique has been applied to a beam of vibrationally cold CH2+ molecular ions and the distribution of bond angles was extracted. From these data, we are able to demonstrate conclusively that the electronic ground state potential of this molecule has a C2v...

  • Aligning molecules with intense nonresonant laser fields. Larsen, Jakob Juul; Sakai, Hirofumi; Safvan, C.P.; Wendt-Larsen, Ida; Stapelfeldt, Henrik // Journal of Chemical Physics;11/1/1999, Vol. 111 Issue 17, p7774 

    Discusses the aligning of molecules with intense nonresonant laser fields. Interaction between an intense nonresonant linearly polarized laser field and the molecular polarizability; Mass selective two dimensional imaging of the photofragment ions produced by femtosecond laser pulses; Future...

  • Molecular Terms and Optical Transitions of C[sub 60][SUP ARRANGE="STAGGER"]n±] Molecular Ions. Nikolaev, A. V.; Michel, K. H. // AIP Conference Proceedings;2002, Vol. 633 Issue 1, p417 

    We have studied the molecular energy terms of the hole configurations (h[SUB u,SUP +])[SUPm] m=2,3,4,5 of C[SUB 60,SUP m+] cations and the electronic configurations (t[SUB1u])[SUPn], n=2,3,4, as well as (t[SUB1u])[SUPn-1]t[SUB1g], of the C[SUB 60,SUP n-] anions. The lowest terms (within an...

  • Electrodynamic acceleration of ultraheavy molecular ions. Sekatskiı, S. K. // Technical Physics Letters;Jul98, Vol. 24 Issue 7, p577 

    The design of an "electrodynamic accelerator" for ultraheavy molecular ions with masses of order 10[sup 6] Da is analyzed. It is shown that these ions can be efficiently accelerated to energies of hundreds of kilo-electronvolts over lengths no greater than 20 cm by using a sequence of voltage...

  • isosmotic.  // Taber's Cyclopedic Medical Dictionary (2009);2009, Issue 21, p1241 

    A definition of the term "isosmotic" which means having the same amount of osmotically active molecules or ions in a solution is presented.

  • The equilibrium properties of charged hard spheres with adhesive interactions between oppositely charged ions. Rasaiah, Jayendran C.; Lee, Song Hi // Journal of Chemical Physics;12/15/1985, Vol. 83 Issue 12, p6396 

    The equilibrium properties of charged hard spheres with adhesive interactions between oppositely charged ions are studied in the hypernetted chain/mean spherical (HNC/MS) approximation and in the Percus–Yevick/Mean spherical (PY/MS) approximation which are solved analytically. Numerical...


Read the Article


Sorry, but this item is not currently available from your library.

Try another library?
Sign out of this library

Other Topics