TITLE

Electrostriction effects on electron transfer reactions in solution. I. Adiabatic regime

AUTHOR(S)
Jonggu Jeon; Kim, Hyung J.
PUB. DATE
April 1997
SOURCE
Journal of Chemical Physics;4/8/1997, Vol. 106 Issue 14, p5979
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Studies the outer-sphere unimolecular electron transfer reactions in polar solvents. Nonequilibrium free energy formulation that accounts for both the solvation and electrostriction aspects of the changing dipole moment during the reaction; Diabatic description of the solute electronic structure; Reaction mechanism and rate constant.
ACCESSION #
4278684

 

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