# The self-consistent statistical theory of condensation

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Transportation and thermodynamic properties of misfit-layered polycrystalline [Ca2CoO3]0.62[CoO2] were measured in order to clarify the nature of metalâ€“ semiconductor transition (MST) at TMSâ‰ˆ400 K, above which the simultaneous decrease of resistivity and increase of thermopower with...

- The virial equation of fluid state and non-classical criticality. Bondarev, V. // European Physical Journal B -- Condensed Matter;Nov2011, Vol. 84 Issue 1, p121
The analysis of fluid criticality in the framework of the 'virial' approach leads, usually, to pure classical results. In the present paper we propose a consistent procedure allowing us to find the non-classical critical parameters of real fluid starting from the representation of the pressure...

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In this work we calculate the shear viscosity Î· in the quark-gluon plasma within a virial expansion approach with particular interest in the ratio of Î· to the entropy density s, i.e. Î·/s. We derive a realistic equation of state using a virial expansion approach which allows us to...

- Fast off-lattice Monte Carlo simulations of soft-core spherocylinders: Isotropic-nematic transition and comparisons with virial expansion. Zong, Jing; Zhang, Xinghua; Wang, Qiang // Journal of Chemical Physics;10/7/2012, Vol. 137 Issue 13, p134904
We proposed a novel anisotropic soft-core potential for spherocylinders that takes into account the degree of overlap between two spherocylinders, thus superior to other soft-core spherocylinder models depending only on the minimum distance between two line segments representing spherocylinders,...

- A curious result concerning the Clausius virial. Powles, J. G.; Rickayzen, G.; Williams, M. L. // Journal of Chemical Physics;7/1/1985, Vol. 83 Issue 1, p293
For a sample of liquid confined in a hard-walled spherical container it is shown by computer simulation and by statistical mechanics that the conventional virial pressure for a notional sphere of radius r is not the correct thermodynamic normal pressure on the surface of the sphere but is the...

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The quantum-mechanical virial theorem is applied to the two-body Dirac equation. It can be used as a powerful test for solutions of this equation. A direct application of the theorem is also given.

- Efficient pressure estimation in molecular simulations without evaluating the virial. Harismiadis, V. I.; Vorholz, J.; Panagiotopoulos, A. Z. // Journal of Chemical Physics;11/8/1996, Vol. 105 Issue 18, p8469
A method for calculating the pressure in molecular simulations that does not require calculation of the virial is proposed, building on earlier work by [R. Eppenga and D. Frenkel, Mol. Phys. 52, 1303 (1984)]. The method requires â€˜â€˜testâ€™â€™ volume changes and it is...

- On the Clausius virial of inhomogeneous systems. Henderson, J. R. // Journal of Chemical Physics;3/15/1986, Vol. 84 Issue 6, p3385
This paper sets out to clarify the nature of the Clausius virial evaluated inside a specified volume of arbitrary geometry and in the presence of a general one-body external field. The standard form of the virial theorem is not obtained when intermolecular forces act across the surface of the...

- Approximate interaction energy in terms of overlap integral. Koga, Toshikatsu; Umeyama, Tatsuya // Journal of Chemical Physics;8/1/1986, Vol. 85 Issue 3, p1433
When the natural orbital expansion is applied to the total wave function, the (electronic) kinetic energy T is exactly expressible in terms of the overlap integral S between the natural orbitals. Then we can derive an implicit but rigorous relation between the total energy E and the overlap...