Real time study of bimolecular interactions: Direct detection of internal conversion involving

Tuchler, Matthew F.; Wright, Scott; McDonald, J. Douglas
February 1997
Journal of Chemical Physics;2/15/1997, Vol. 106 Issue 7, p2634
Academic Journal
Focuses on the formation of a reaction complex from a van der Waals dimer precursor, HBr.I[sub 2], monitored with time resolution using standard pump-probe spectroscopy. Initiation of the reaction in an attractive region of an excited electronic state with insufficient energy to fragment; Detection of an isotope effect; Temporal discrepancies in risetimes.


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