Kinetics and dynamics in the photodissociation of the allyl radical

Deyeri, Hans-Jurgen; Gilbert, Thomas; Fischer, Ingo; Chen, Peter
August 1997
Journal of Chemical Physics;8/22/1997, Vol. 107 Issue 8, p3329
Academic Journal
Reports on the direct observation of the products, kinetics and transitional energy release from the photodissociation of the allyl radical upon excitation in the near-ultraviolet. Allene formation being the dominant hydrogen-loss reaction channel; Appearance of hydrocarbon radicals as chemical intermediates in many reactive environments.


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