Aspects of sorption and phase behavior of near-critical fluids confined to mesoporous media

Schoen, Martin; Thommes, Matthias; Findenegg, Gerhard H.
August 1997
Journal of Chemical Physics;8/22/1997, Vol. 107 Issue 8, p3262
Academic Journal
Investigates the local structure of a Lennard-Jones fluid confined to a mesoscopic slit-pore with structureless walls. Computation of local density in grand canonical ensemble Monte Carlo (GCEMC) simulations; Depletion's relation to a reduced degree of criticality of the core fluid; Homogeneous core region in the pore characterized by bulk density.


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