The short-time intramolecular dynamics of solutes in liquids. II. Vibrational population relaxation

Goodyear, Grant; Stratt, Richard M.
August 1997
Journal of Chemical Physics;8/22/1997, Vol. 107 Issue 8, p3098
Academic Journal
Discusses the treatment of vibrational friction and vibrational relaxation dynamics within an instantaneous normal mode (INM) formalism. Formulation of an INM generalized Langevin equation; INM predictions for vibrational friction kernels, line shapes and dynamics; Role of solute-solvent inhomogeneities in vibrational dynamics.


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