The potential surface for the three methyl rotations in the tertiary-butyl cation,

East, Allan L. L.
September 1997
Journal of Chemical Physics;9/8/1997, Vol. 107 Issue 10, p3914
Academic Journal
Examines the intricate symmetry of the potential energy surface for the three methyl rotation dimensions in the tertiary-butyl cation. Four-parameter model similar to a form commonly used in the studies of two-rotor systems; Values of a 14-parameter function; Total energy distribution analyses of ab initio harmonic force fields.


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