Vibrational anharmonicity and multilevel vibrational dephasing from vibrational echo beats

Rector, K.D.; Kwok, A.S.; Ferrante, C.; Tokmakoff, A.; Rella, C.W.; Fayer, M.D.
June 1997
Journal of Chemical Physics;6/22/1997, Vol. 106 Issue 24, p10027
Academic Journal
Reports that vibrational echo experiments were performed on the IR active CO stretching modes of rhodium dicarbonylacetylacetonate and tungsten hexacarbonyl in dibutylphthalate and a mutant of myoglobin-CO in glycerol-water using ps IR pulses from a free electron laser. Nature of the experiment and procedures; Vibrational echo decay for asymmetric CO stretching mode.


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