TITLE

Electric field-gradient contributions to the chemical shifts of liquid water

AUTHOR(S)
Nymand, Thomas M.; Astrand, Per-Olof
PUB. DATE
May 1997
SOURCE
Journal of Chemical Physics;5/22/1997, Vol. 106 Issue 20, p8332
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Focuses on contributions to gas-to-liquid chemical shifts of water arising from the electric field gradient of the surrounding molecules as a function of the temperature. Theoretical model based on perturbation theory; Calculation of chemical shift from quadrupole shielding polarizabilities and statistical mechanical ensemble averages of external electric field-gradients.
ACCESSION #
4222428

 

Related Articles

  • Fluid dynamics of a double emulsion droplet in an electric field. Ha, Jong-Wook; Yang, Seung-Man // Physics of Fluids;May99, Vol. 11 Issue 5, p1029 

    Examines the fluid dynamics of a double emulsion droplet in an electric field. Constituent phases of leaky dielectric fluids; Use of the domain perturbation procedure; Characterization of patterns of electric-field-driven flow.

  • NONLINEAR ALTERNATING CURRENT RESPONSES IN ELECTRORHEOLOGICAL FLUIDS:: DYNAMIC EFFECTS. YU, K. W.; TIAN, W. J.; HUANG, J. P. // International Journal of Modern Physics B: Condensed Matter Phys;11/10/2007, Vol. 21 Issue 28/29, p4825 

    By using a perturbation approach, we investigate dynamic effects on nonlinear alternating current (ac) responses in electrorheological (ER) fluids under an ac or a direct current electric field. We show that the dynamic effect due to a shear flow plays a significant role in the responses. Our...

  • Nonlinear regime of a multimode Richtmyer–Meshkov instability: A simplified perturbation theory. Vandenboomgaerde, Marc; Gauthier, Serge; Mu¨gler, Claude // Physics of Fluids;Mar2002, Vol. 14 Issue 3, p1111 

    In this paper we present a drastic simplification of the perturbation method for the Richtmyer-Meshkov instability developed by Zhang and Sohn [Phys. Fluids 9, 1106 (1997)]. This theory is devoted to the calculus of the growth rate of the perturbation of the interface in the weakly nonlinear...

  • Translational instability of a bubble undergoing shape oscillations. Feng, Z.C.; Leal, L.G. // Physics of Fluids;Jun95, Vol. 7 Issue 6, p1325 

    Studies the translational instability of an oscillating bubble. Perturbation analysis; Derivation of amplitude equations; Insignificance of integral relations for motions of bubbles in an infinite perfect liquid; Intimate coupling between the translational motions and amplitudes.

  • Axisymmetrization of an isolated vortex region by splitting and partial merging of satellite... Yao, H.B.; Zabusky, N.J. // Physics of Fluids;Jul96, Vol. 8 Issue 7, p1842 

    Reports on the application of numerical methods to obtain a similar downward cascade or symmetrization phenomena. Observation of essentially inviscid approach to axisymmetry of an isolated-and-perturbed monopolar and uniformly decreasing disturbed vortex region in a two-dimensional...

  • Nonsolenoidal flow in a liquid diffusion couple. Perera, P.S.; Sekerka, R.F. // Physics of Fluids;Feb97, Vol. 9 Issue 2, p376 

    Focuses on the advective nonsolenoidal flow driven by diffusion-induced density changes in strictly zero gravity in a two-dimensional rectangular box. Perturbation expansions of mass fraction of the second chemical component of a binary solution; Total barycentric velocity field.

  • Viscous nonlinear theory of Richtmyer-Meshkov instability. Carles, Pierre; Popinet, Stéphane // Physics of Fluids;Jul2001, Vol. 13 Issue 7, p1833 

    We propose a quantitative prediction of the effect of viscosity on the weakly nonlinear impulsive Richtmyer-Meshkov instability between two fluids of arbitrary density and viscosity. This theory is based on an asymptotic analysis of the Navier-Stokes equations using singular perturbation...

  • Breakup length of forced liquid jets. Kalaaji, A.; Lopez, B.; Attané, P.; Soucemarianadin, A. // Physics of Fluids;Sep2003, Vol. 15 Issue 9, p2469 

    The experimental breakup of liquid jets subjected to a sinusoidal perturbation is investigated in the Rayleigh and first wind-induced regimes. Stroboscopic illumination of the jet and laser photometry method are used. The ability of linear spatial and temporal theories to describe certain...

  • Increase in the hydraulic pressure in various zones of a two-fluid hydrophilic capillary due to nonuniformity of the external electric field. Tikhomolov, D. V.; Slyadneva, O. N. // Technical Physics;Aug98, Vol. 43 Issue 8, p898 

    The phenomenon whereby the thickness of the water film next to the inner surface of a hydrophilic capillary filled with two fluids increases in the presence of an external static electric field is investigated. A hypothesis of the essential nature of the phenomenon is submitted, along with a...

Share

Read the Article

Courtesy of THE LIBRARY OF VIRGINIA

Sorry, but this item is not currently available from your library.

Try another library?
Sign out of this library

Other Topics