TITLE

Combined high resolution infrared and microwave study of bromochlorofluoromethane

AUTHOR(S)
Bauder, Alfred; Beil, Andreas
PUB. DATE
May 1997
SOURCE
Journal of Chemical Physics;5/8/1997, Vol. 106 Issue 18, p7558
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Details a spectroscopic investigation of the chiral molecule bromochlorofluoromethane with rotational resolution using a pulsed nozzle beam Fourier transform microwave (FTMW) and a waveguide FTMW spectrometer as a supersonic jet interferometric Fourier transform infrared (FTIR) and infrared diode laser spectrometer. Effective Hamiltonians used in the analyses.
ACCESSION #
4212309

 

Related Articles

  • Intensities in the ν7, ν8, and ν9 bands of CH2NH and the harmonic force field of methyleneimine. Halonen, L.; Deeley, C. M.; Mills, I. M. // Journal of Chemical Physics;7/15/1986, Vol. 85 Issue 2, p692 

    A high resolution Fourier transform infrared spectrum of methyleneimine, HN=CH2, has been obtained in the gas phase in the region 700 to 1300 cm-1. The rovibrational line intensities of the three lowest fundamentals ν7 (A’), ν8 (A‘), and ν9 (A‘) have been simulated...

  • The initial product vibrational energy distribution in the reaction between O(1D2) and H2. Aker, P. M.; Sloan, J. J. // Journal of Chemical Physics;8/1/1986, Vol. 85 Issue 3, p1412 

    We report the first determination of the initial vibrational distribution in the OH product of the reaction between O(1D2) and H2. The measurement was made using a novel time-resolved Fourier transform spectroscopic technique which permits the observation of spectra on a microsecond time scale...

  • Rotational spectra and structures of small clusters containing the HCN dimer: (HCN)2–Ar, a T-shaped trimer. Ruoff, R. S.; Emilsson, T. I.; Klots, T. D.; Chuang, C.; Gutowsky, H. S. // Journal of Chemical Physics;2/1/1988, Vol. 88 Issue 3, p1557 

    Microwave rotational spectra have been observed for the four 14N/15N isotopic species of an (HCN)2–Ar trimer with the pulsed nozzle Fourier transform method using the Flygare Mark II spectrometer. Thirteen J→J’ asymmetric top transitions were measured in the 2.5 to 10 GHz...

  • Spectral averaging and low-frequency sampling modifications for the IQS 401 fast Fourier transform spectrum analyzer. Smith, Steven W. // Review of Scientific Instruments;Jan1985, Vol. 56 Issue 1, p159 

    The IQS 401 spectrum analyzer, a commercial addition to the Apple II and III personal computers, can be modified for low-cost power spectrum measurements of random noise signals and similar waveforms. The IQS basic control program is changed to perform low-frequency sampling, spectral averaging,...

  • Temperature-resolved derivative FTIR. Androsch, R.; Kolesov, I.; Radusch, H.-J. // Journal of Thermal Analysis & Calorimetry;2003, Vol. 73 Issue 1, p59 

    The fine-structure of the 720/730 cm-1 doublet of FTIR spectra has been evaluated by derivative spectroscopy as function of temperature on low-density poly(ethylene-co-1-octene). The pseudo-hexagonal mesophase in polyethylene, obtained at atmospheric pressure, is a non-equilibrium phase which...

  • Note: Phase sensitive detection of photoluminescence with Fourier transform spectroscopy. Ullrich, B.; Brown, G. J. // Review of Scientific Instruments;Jan2012, Vol. 83 Issue 1, p016105 

    Although known for more than twenty years, there is limited information in the literature regarding the experimental parameters of lock-in based phase sensitive emission detection in conjunction with Fourier spectrometers. For this technique - also known as double modulation spectroscopy - we...

  • Continual in-plane displacement measurement with temporal wavelet transform speckle pattern interferometry. Gao, Zhan; Deng, Yan; Duan, Yiting; Zhang, Zhifeng; Wei, Cheng; Chen, Shiqian; Cui, Jianying; Feng, Qibo // Review of Scientific Instruments;Jan2012, Vol. 83 Issue 1, p015107 

    A heterodyne temporal speckle pattern interferometer that measures the in-plane displacement dynamically has been built. The object is displaced in its plane continuously and the frequency-modulated output signals with a carrier frequency are recorded by a CCD camera. The displacement...

  • Electrical and physical properties of NaO-CaO-MgO-SiO glass doped with NdF. Darwish, H.; Ibrahim, S.; Gomaa, M. // Journal of Materials Science: Materials in Electronics;Mar2013, Vol. 24 Issue 3, p1028 

    The structure of soda-calcia-magnesia-silicate glasses doped with rare-earth fluoride (NdF) was investigated by Fourier transform infrared spectrometer. The density and microhardness have been investigated in order to study the effect of doping NdF on the physical properties of the studied...

  • Infrared in the Real World -- How It Will Evolve in the New Millennium. Wilks, Paul; MacRae, Michael // Spectroscopy;Dec1999, Vol. 14 Issue 12, p12 

    Editorial. Traces the historical development of commercial infrared spectroscopy. Description of spectrometers; Advent of the Fourier transform-infrared spectrometer; Research on near-infrared portion of the spectrum.

Share

Read the Article

Courtesy of THE LIBRARY OF VIRGINIA

Sorry, but this item is not currently available from your library.

Try another library?
Sign out of this library

Other Topics