TITLE

Reversible control of the nonlinear optical activity of one-dimensional metal complexes

AUTHOR(S)
Kamata, T.; Fukaya, T.
PUB. DATE
September 1994
SOURCE
Applied Physics Letters;9/12/1994, Vol. 65 Issue 11, p1343
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Demonstrates the reversible controllability of the third-order nonlinear optical activity on a one-dimensional metal complex. Disappearance of the d-p transition absorption band of the metal complex; Decline of two-odd orders in the third-order nonlinear susceptibility; Restoration of the deactivated optical nonlinearity by removing iodine from the film.
ACCESSION #
4203795

 

Related Articles

  • Third-order susceptibilities of asymmetric pentaazadentate porphyrin-line metal complexes. Wenfang Sun; Byeon, Clare C. // Applied Physics Letters;5/31/1999, Vol. 74 Issue 22, p3254 

    Studies the third-order nonlinear optical properties of a series of asymmetric pentaazadentate porphyrin-like metal complexes with different R groups and metal centers. Molecular second-order hyperpolarizabilities for the complexes; Most promising nonlinear optical materials for optical...

  • Crystal structure, spectroscopic studies, and nonlinear optical (NLO) properties of Schiff base metal complexes containing an N, S donor ligand. Zhao-Ming Xue; Ying-Wen Tang; Jie-Ying Wu; Yu-Peng Tian; Min-Hua Jiang; Fun, H.-K.; Usman, A. // Canadian Journal of Chemistry;Dec2004, Vol. 82 Issue 12, p1700 

    A new ligand, 4-dipropylaminobenzaldehyde thiosemicarbazone (abbreviated as HL), and its complexes ML2 (M = Ni, Pd, and Cu) have been synthesized and fully characterized by elemental analyses, EI-MS, IR and UV–vis spectroscopy, and photoluminescence measurements. All of the compounds...

  • Structural, spectral and mechanical studies of bimetallic crystal: cadmium manganese thiocyanate single crystals. Manikandan, M.; Vijaya Prasath, G.; Bhagavannarayan, G.; Vijayan, N.; Mahalingam, T.; Ravi, G. // Applied Physics A: Materials Science & Processing;Sep2012, Vol. 108 Issue 4, p1015 

    A nonlinear optical bimetallic thiocyanate complex crystal, cadmium manganese thiocyanate (CMTC) has been successfully synthesized. The growth of single crystals of cadmium manganese thiocyanate has been accomplished from aqueous solution using slow evaporation method. The presence of manganese...

  • Metal-Based NLO Chromophores: from Tuning to Switching the Quadratic Nonlinearities. Le Bozec, H.; Guerchais, V.; Akdas-Kilig, H.; Maury, O.; Ordronneau, L.; Boucekkine, A.; Singh, A.; Ledoux, I.; Zyss, J. // Nonlinear Optics, Quantum Optics: Concepts in Modern Optics;2012, Vol. 43 Issue 1-4, p187 

    This article discusses the second-order nonlinear optical properties of a series of dipolar bis(dibutylaminostyryl) bipyridine M(II) dichloride complexes (M = Co, Ni, Cu, Zn) and octupolar tris(bipyridine) M(II) complexes of D3 symmetry (M = Fe, Ru, Os, Ni, Cu, Zn). Their quadratic...

  • The Relevance of the Octupolar Contribution to the Quadratic Hyperpolarizability of Dipolar Neutral Ir(III), Pt(II) and Ru(II) Complexes. Dragonetti, Claudia; Righetto, Stefania; Roberto, Dominique; Ugo, Renato; Valore, Adriana; Ledoux-Rak, Isabelle // Nonlinear Optics, Quantum Optics: Concepts in Modern Optics;2012, Vol. 43 Issue 1-4, p197 

    Various neutral dipolar Ir(III), Pt(II) and Ru(II) complexes characterized by a high µβ 1.907 value, as determined by the Electric Field Induced Second Harmonic generation (EFISH) technique, show a large <βHLS,1.907>, as determined by the Harmonic Light Scattering (HLS) technique. A...

  • Theoretical study of solvent and substituent effects on the structure, N NQR and electronic spectra of [Cr(CO)py]. Fashami, M.; Ghiasi, R.; Pasdar, Hoda // Journal of Structural Chemistry;Dec2015, Vol. 56 Issue 8, p1474 

    The structure, N NQR parameters, electronic spectra, and hyperplarizability of [Cr(CO)py] in seven different solvents were theoretically computed with MPW1PW91 method based on Polarizable Continuum Model (PCM). The substituent effects in para- substituted Cr(CO)-pyridine complexes have been...

  • Synthesis, Characterization and Third Order Nonlinear Optical Studies of Diimine Based Zn(II), Cd(II) and Hg(II) Complexes. Rudresha, B. J.; Bhat, B. Ramachandra; Manjunatha, K. B.; Umesh, G. // AIP Conference Proceedings;10/20/2011, Vol. 1391 Issue 1, p697 

    The Zn(II), Cd(II), Hg(II) complexes bearing diimine and one-dimensional (1D) push-pull NLO-phores with π-conjugation between ligands and metal have been synthesized for two-dimensional (2D) nonlinear optical response. The third-order nonlinear optical properties of complexes were studied...

  • Investigations on Metal Complexes of Thiourea for Frequency Conversion and Low Power Optical Limiting Applications. Girisun, T. C. Sabari; Dhanuskodi, S.; Phillip, J. // AIP Conference Proceedings;10/20/2011, Vol. 1391 Issue 1, p535 

    Good quality single crystals of metal complexes of thiourea with II group transition metals (Zn, Cd) as central atom and III period element (Cl) were grown from aqueous solution by slow evaporation method. Their structural, optical, thermal and dielectric properties were investigated and...

  • Electro optic devices look to nonlinear materials. Studt, Tim // R&D Magazine;Apr95, Vol. 37 Issue 5, p31 

    Reports on the potentials of nonlinear optical materials in optical switching for fiber optic communications, optical computer disconnects and optical computing. Approaches to NLO fabrication that are under investigation; Cost savings from the technology; Organizations involved in the...

Share

Read the Article

Courtesy of VIRGINIA BEACH PUBLIC LIBRARY AND SYSTEM

Sorry, but this item is not currently available from your library.

Try another library?
Sign out of this library

Other Topics