Optimized cluster theory of polymer blends: General formulation and application to isotopic

Melenkevitz, J.; Curro, J.G.
January 1997
Journal of Chemical Physics;1/15/1997, Vol. 106 Issue 3, p1216
Academic Journal
Details a theory for the thermodynamic properties of binary polymer blends to predict the compositional dependence of the effective chi parameter X(sub s) in isotopic polyethylene mixtures. Generalization of the optimized cluster theory for single component molecular fluids; Exact cluster expansions for the Helmholtz free energy and pair-correlation functions.


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