Vibrational energy relaxation of diatomic molecules in rare gas crystals

Egorov, S.A.; Skinner, J.L.
January 1997
Journal of Chemical Physics;1/15/1997, Vol. 106 Issue 3, p1034
Academic Journal
Describes a theory for state-to-state vibrational multiphoton relaxation rates for diatomic molecule in a rare gas crystal. Interaction between the diatomic and host atoms modeled with a Lennard-Jones potential; Nonlinear coupling between anharmonic vibration of the diatomic and the acoustic phonons of the crystal.


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