TITLE

Quantum dynamics of the Walden inversion reaction Cl[sup -]+CH[sub 3]Cl...CICH[sub 3]+Cl[sup -]

AUTHOR(S)
Clary, David C.; Palma, Juliana
PUB. DATE
January 1997
SOURCE
Journal of Chemical Physics;1/8/1997, Vol. 106 Issue 2, p575
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Focuses on the quantum scattering calculations of the Walden inversion reaction Cl [sup -] + CH [sub 3]Cl-> ClCH [sub 3] + Cl [sup -]. Adaptation of the rotating bond approximation; Effect of the initial excitation of the carbon-chlorine vibration on reaction probabilities; Dominance of reaction by scattering resonances.
ACCESSION #
4163186

 

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