Laser velocity modulation spectroscopy of the [sup 3]delta(3d4s)-X[sup 3]phi(3d[sup 2]) visible

Focsa, C.; Dufour, C.
June 1997
Journal of Chemical Physics;6/8/1997, Vol. 106 Issue 22, p9044
Academic Journal
Describes the first extensive experimental characterization of the electronic, vibrational and rotational structure of titanium chloride leading to the determination of the relative positions of the spin-orbit components of the two electronic states. Observed bands; Use of the velocity modulation technique to record absorption spectrum.


Related Articles

  • The vibration-rotation spectrum of the hydroxide anion (OH-). Owrutsky, Jeffrey C.; Rosenbaum, Neil H.; Tack, Leslie M.; Saykally, Richard J. // Journal of Chemical Physics;11/15/1985, Vol. 83 Issue 10, p5338 

    Discusses studies on the vibration rotation-spectrum of the hydroxide anions. Features of the velocity modulation method which has been described previously in connection with studies of molecular cations; Discussion on the spectra of hydroxide anions; Surprising result of the first measurement...

  • Velocity modulation laser absorption spectroscopy of the A [sup 2]Π[sub i]←X [sup 2]Σ[sup +] transition of the CS[sup +] cation. Liu, Yuyan; Duan, Chuanxi; Liu, JinJun; Wu, Ling; Xu, Chaoxiong; Chen, Yangqin; Hamilton, P. A.; Davies, P. B. // Journal of Chemical Physics;6/8/2002, Vol. 116 Issue 22, p9768 

    The laser absorption spectrum of the (5,0) and (6,0) bands of the A[sup 2]π[sub i]→X[sup 2]&sigma[sup +] transition of CS[sup +] has been recorded using velocity modulation spectroscopy enhanced by optical heterodyne and magnetic rotation effects. First, improved molecular constants...

  • Optical heterodyne magnetic rotation enhanced velocity modulation spectroscopy: A sensitive absorption-based scheme for paramagnetic molecular ions. Luo, Ming; Bi, Zhiyi; Cai, Peipei; Wang, Rongjun; Yang, Xiaohua; Chen, Yangqin; Ma, Longsheng // Review of Scientific Instruments;Jun2001, Vol. 72 Issue 6, p2691 

    The sensitivity of velocity modulation spectroscopy (VMS) has been greatly improved by use of the frequency modulation enhanced magnetic rotation spectroscopic (FM-MRS) technique. This technique, which we refer to as optical heterodyne magnetic rotation enhanced VMS, has been described in detail...

  • Arc Deposited TiAlN Selective Absorber for High Temperature CSP Applications. Bichotte, M.; Dubost, L.; Pouit, T.; Soum-Glaude, A.; Le Gal, A.; Glenat, H.; Itskhokine, David // AIP Conference Proceedings;2016, Vol. 1734 Issue 1, p1 

    The paper presents preliminary results of a partnership project between academic research groups and industrial partners. The LFR500 project aims at developing a prototype of Linear Fresnel Reflector (LFR) solar power plants able to work above 500?C providing Direct Steam Generation (DSG) under...

  • X-ray fluorescence method for determining the mass absorption coefficient in two-layer thin-film Ti/Ge and Ni/Ge systems. Mashin, N.; Lebedeva, R.; Tumanova, A.; Ershov, A. // Journal of Applied Spectroscopy;May2012, Vol. 79 Issue 2, p307 

    We propose a new method for determining the mass absorption coefficient in x-ray fluorescence analysis of two-layer thin-film Ti/Ge and Ni/Ge systems using easily made standardized film layers obtained by deposition of titanium or nickel on a polymer film substrate. We calculate correction...

  • Effect of a velocity gradient on the shear viscosity of a solution in the critical region. Vaınshteın, L. V.; Krivokhizha, S. V.; Chaıkov, L. L. // JETP Letters;7/10/97, Vol. 66 Issue 1, p1 

    An experimental study is made of the effect of a gradient of the fluid velocity on the value of the shear viscosity in a critical guaiacolglycerin solution with a stratification region as the lower critical temperature for stratification is approached. It is shown that the interaction of...

  • Infrared spectrum of the ν2 vibration-inversion band of H3O+. Liu, Di-Jia; Haese, Nathan N.; Oka, Takeshi // Journal of Chemical Physics;6/15/1985, Vol. 82 Issue 12, p5368 

    High resolution infrared spectra of the 1-←0+ and 1+←0- ν2 vibration-inversion bands of H3O+ have been observed in the ac glow discharge by using tunable diode lasers and the velocity modulation technique. The two band origins were found to be at 954.4003(25) and 525.8237(13) cm-1...

  • Measurement of the ν1 vibration-rotation spectrum of the thioformyl ion (HCS+) by velocity modulation laser spectroscopy. Rosenbaum, Neil H.; Owrutsky, Jeffrey C.; Tack, Leslie M.; Saykally, Richard J. // Journal of Chemical Physics;11/15/1985, Vol. 83 Issue 10, p4845 

    The measurement and analysis of the C–H stretching vibration (ν1) of HCS+ is reported. Eighty transitions [R(0)–R(44), P(1)–P(35)] were measured near 3.2 μm with a color center laser by the velocity modulation technique in a He/CO/H2S plasma. The ν1 band origin is...

  • Velocity modulation in focused-ion-beam written in-plane-gate transistors. Bever, T.; Klitzing, K.V. // Applied Physics Letters;8/2/1993, Vol. 63 Issue 5, p642 

    Examines the velocity modulation of focused-ion-beam written in-plane gates (IPG). Details of several IPG transistor designs; Effects of IPG transistor symmetry on the gates; Change of the current path from high mobility to low mobility channel.


Read the Article


Sorry, but this item is not currently available from your library.

Try another library?
Sign out of this library

Other Topics