TITLE

Laser velocity modulation spectroscopy of the [sup 3]delta(3d4s)-X[sup 3]phi(3d[sup 2]) visible

AUTHOR(S)
Focsa, C.; Dufour, C.
PUB. DATE
June 1997
SOURCE
Journal of Chemical Physics;6/8/1997, Vol. 106 Issue 22, p9044
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Describes the first extensive experimental characterization of the electronic, vibrational and rotational structure of titanium chloride leading to the determination of the relative positions of the spin-orbit components of the two electronic states. Observed bands; Use of the velocity modulation technique to record absorption spectrum.
ACCESSION #
4149085

 

Related Articles

  • The vibration-rotation spectrum of the hydroxide anion (OH-). Owrutsky, Jeffrey C.; Rosenbaum, Neil H.; Tack, Leslie M.; Saykally, Richard J. // Journal of Chemical Physics;11/15/1985, Vol. 83 Issue 10, p5338 

    Discusses studies on the vibration rotation-spectrum of the hydroxide anions. Features of the velocity modulation method which has been described previously in connection with studies of molecular cations; Discussion on the spectra of hydroxide anions; Surprising result of the first measurement...

  • Velocity modulation laser absorption spectroscopy of the A [sup 2]Π[sub i]←X [sup 2]Σ[sup +] transition of the CS[sup +] cation. Liu, Yuyan; Duan, Chuanxi; Liu, JinJun; Wu, Ling; Xu, Chaoxiong; Chen, Yangqin; Hamilton, P. A.; Davies, P. B. // Journal of Chemical Physics;6/8/2002, Vol. 116 Issue 22, p9768 

    The laser absorption spectrum of the (5,0) and (6,0) bands of the A[sup 2]π[sub i]→X[sup 2]&sigma[sup +] transition of CS[sup +] has been recorded using velocity modulation spectroscopy enhanced by optical heterodyne and magnetic rotation effects. First, improved molecular constants...

  • Optical heterodyne magnetic rotation enhanced velocity modulation spectroscopy: A sensitive absorption-based scheme for paramagnetic molecular ions. Luo, Ming; Bi, Zhiyi; Cai, Peipei; Wang, Rongjun; Yang, Xiaohua; Chen, Yangqin; Ma, Longsheng // Review of Scientific Instruments;Jun2001, Vol. 72 Issue 6, p2691 

    The sensitivity of velocity modulation spectroscopy (VMS) has been greatly improved by use of the frequency modulation enhanced magnetic rotation spectroscopic (FM-MRS) technique. This technique, which we refer to as optical heterodyne magnetic rotation enhanced VMS, has been described in detail...

  • X-ray fluorescence method for determining the mass absorption coefficient in two-layer thin-film Ti/Ge and Ni/Ge systems. Mashin, N.; Lebedeva, R.; Tumanova, A.; Ershov, A. // Journal of Applied Spectroscopy;May2012, Vol. 79 Issue 2, p307 

    We propose a new method for determining the mass absorption coefficient in x-ray fluorescence analysis of two-layer thin-film Ti/Ge and Ni/Ge systems using easily made standardized film layers obtained by deposition of titanium or nickel on a polymer film substrate. We calculate correction...

  • On the elimination of wall-topography parameters from second-moment closure. Launder, B. E.; Li, S.-P. // Physics of Fluids;Feb94, Vol. 6 Issue 2, p999 

    Current generation second-moment closures employ wall proximity/orientation parameters to ensure that the velocity fluctuations normal to the wall die out as the wall is approached faster than fluctuations parallel to the wall. The use of such devices renders the models unsuitable for...

  • Negative differential conductivity in electron-beam irradiated Ar-HCl mixtures. Lando, M.; Rozenberg, Z.; Rokni, M. // Journal of Applied Physics;2/15/1987, Vol. 61 Issue 4, p1667 

    Presents a study that reported the measurements of the drift velocity in electron-beam irradiated argon/hydrochloride (HCl) mixtures and the occurrence of negative differential conductivity (NDC) in those mixtures. Description of NDC; Rate of reduction of the HCl density in the experimental...

  • Effect of a velocity gradient on the shear viscosity of a solution in the critical region. Vaınshteın, L. V.; Krivokhizha, S. V.; Chaıkov, L. L. // JETP Letters;7/10/97, Vol. 66 Issue 1, p1 

    An experimental study is made of the effect of a gradient of the fluid velocity on the value of the shear viscosity in a critical guaiacolglycerin solution with a stratification region as the lower critical temperature for stratification is approached. It is shown that the interaction of...

  • Ultrafast polarization-discriminating Mach-Zehnder all-optical switch. Tajima, K.; Nakamura, S. // Applied Physics Letters;12/18/1995, Vol. 67 Issue 25, p3709 

    Proposes a polarization-discriminating Mach-Zehnder semiconductor all-optical switch. Capability of the ultrafast and high repetition rate operation; Demonstration of the square-like modulation characteristics at 4 picosecond switching speed; Description of the ultrafast switching at a detector...

  • Infrared spectrum of the ν2 vibration-inversion band of H3O+. Liu, Di-Jia; Haese, Nathan N.; Oka, Takeshi // Journal of Chemical Physics;6/15/1985, Vol. 82 Issue 12, p5368 

    High resolution infrared spectra of the 1-←0+ and 1+←0- ν2 vibration-inversion bands of H3O+ have been observed in the ac glow discharge by using tunable diode lasers and the velocity modulation technique. The two band origins were found to be at 954.4003(25) and 525.8237(13) cm-1...

Share

Read the Article

Courtesy of THE LIBRARY OF VIRGINIA

Sorry, but this item is not currently available from your library.

Try another library?
Sign out of this library

Other Topics