TITLE

Molybdenum and Tungsten Tricarbonyl Complexes of Isatin with Triphenylphosphine

AUTHOR(S)
Khalil, M. M. H.; Al-Seif, F. A.
PUB. DATE
January 2008
SOURCE
Research Letters in Inorganic Chemistry;2008, p1
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Reaction of M(CO)6; M = Mo or W with isatin in the presence of triphenylphosphine in THF under reduced pressure gave the tricarbonyl derivatives complexes [M(CO)3(isatH)(PPh3)]. The two complexes were characterized by elemental analysis, infrared, mass and 1H NMR spectroscopy. The spectroscopic studies show that the two complexes exist in fac- and merisomers in solutions through exchange the CO group and PPh3. The Uv-Vis spectra of the complexes in different solvents were studied.
ACCESSION #
37551383

 

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