TITLE

Rhodium-Catalyzed C-C Bond Cleavage Reactions

AUTHOR(S)
Necas, David; Kotora, Martin
PUB. DATE
November 2007
SOURCE
Current Organic Chemistry;Nov2007, Vol. 11 Issue 17, p1566
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Rhodium complexes have found a wide application in the catalytic C-C bond activation of various substrates depending on the ligand environment. The reaction proceeds with strained carbocycles (cyclopropanes, cyclobutanes and their derivatives), with non-strained C-C bonds activated by carbonyl or other functionalities, or it can result in decarbonylation (aldehydes, acyl halides etc.). Rhodium catalyzed C-C bond cleavage reactions were also used as key steps in syntheses of several natural compounds or biologically active molecules.
ACCESSION #
27363309

 

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