TITLE

Iron fractionation for corrosion products from natural gas pipelines by continuous-flow sequential extraction

AUTHOR(S)
Kaewkhomdee, Nattikarn; Kalambaheti, Chatvalee; Predapitakkun, Somrudee; Siripinyanond, Atitaya; Shiowatana, Juwadee
PUB. DATE
October 2006
SOURCE
Analytical & Bioanalytical Chemistry;Oct2006, Vol. 386 Issue 2, p363
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The forms and quantities of iron species in corrosion product samples from natural gas pipelines were examined, using a continuous-flow sequential extraction system. Sequential extraction consists of four steps that dissolve water soluble iron (FeSO4), acid soluble iron (FeCO3), reducible iron (Fe-(oxyhydr)oxides) and oxidisable iron (FeS2) fractions, respectively. Selectivity of extracting reagents for particular iron species was evaluated by determination of co-extracted anions, using ion chromatography, and evolved CO2, using indirect flame atomic absorption spectrometer (FAAS). Iron was found predominantly in the reducible fraction (61–99%), indicating that Fe-(oxyhydr)oxides are the major constituents of the corrosion products. [Figure not available: see fulltext.]
ACCESSION #
22164392

 

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