TITLE

Spatially resolved in situ measurements of the transport of organic molecules in a polycrystalline nanoporous membrane

AUTHOR(S)
Weontae Oh; Nair, Sankar
PUB. DATE
October 2005
SOURCE
Applied Physics Letters;10/10/2005, Vol. 87 Issue 15, p151912
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
We report spatially resolved, quantitative, in situ, nondestructive measurements of the transport of organic molecules through a polycrystalline, anisotropic, nanoporous molecular sieve membrane, with micron-scale resolution. A method based on photoacoustic spectroscopy experiments during permeation through a nanoporous membrane, combined with a physical model of photoacoustic signal generation from a heterogeneous membrane, allows extraction of concentration profiles in situ. In particular, we demonstrate the steady-state concentration profiling of the organic molecules p-xylene and n-hexane during their transport through a nanoporous zeolite silicalite membrane. The implications for elucidating structure-property relationships in membrane materials for separations, catalytic, or nanotechnology applications are discussed.
ACCESSION #
18856899

 

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